ЙМОВІРНИЙ МЕХАНІЗМ СОНОКАТАЛІТИЧНОЇ АКТИВАЦІЇ КАЛІЮ ПЕРОКСОДИСУЛЬФАТУ ДЛЯ ДЕГРАДАЦІЇ БАРВНИКА САФРАНІНУ Т
DOI:
https://doi.org/10.31319/2519-2884.45.2024.19Ключові слова:
сонокаталітична активація, калію пероксодисульфат, наночастинки шпінелі, барвник, синглетний кисеньАнотація
і методи активації персульфатів (пероксомоносульфатів і пероксодисульфатів). Запропоновано здійснювати деградацію сафраніну Т із використанням калію пероксодисульфату (K2S2O8), активованого в ультразвуковому кавітаційному полі та наночастинками шпінелі MnFe2O4 (сонокаталітична активація). Встановлено, що зі збільшенням температури реакційного середовища від 393 до 433 К ступінь деградації барвника зростав від 77,7 до 98,3 %, що свідчило про вагому роль температури як третього фактора активації K2S2O8. З’ясовано, що окиснювальна деградація сафраніну Т найбільш достовірно описується кінетичним рівнянням реакції другого порядку. Методом “спінових пасток” ідентифіковано домінантну активну форму Кисню — синглетний кисень.
Посилання
Hassan A.F., Alshandoudi L.M., Awad A.M., Mustafa A.A., Esmail G. Synthesis of nanomagnetite/copper oxide/potassium carrageenan nanocomposite for the adsorption and Photo Fenton degradation of Safranin O: kinetic and thermodynamic studies. Macromolecular Research. 2023. Vol. 31. P. 677—697. doi.org/10.1007/s13233-023-00147-4
Salem M.A., Salem I.A., Zaki H.M., El-Sawy A.M. Elimination of Safranin-O and a binary mixture of Safranin-O and methylene blue from water by adsorption on magnetite/Ag nanocomposite. Egyptian Journal of Petroleum. 2022. Vol. 31. No. 2. P. 39—49. doi.org/10.1016/j.ejpe.2022.05.002
Bendjama M., Hamdaoui O., Ferkous H., Alghyamah A. Degradation of safranin O in water by UV/TiO2/IO4- process: Effect of operating conditions and mineralization. Catalysts. 2022. Vol. 12(11). 1460. doi.org/10.3390/catal12111460
Jadhav G.K.P., Malusare O.S.A., Ahiwale R.K.P., Patil P., Grouli A., Berrada M., Pandit V.R.U. Safranin dye degradation by using Fe2O3-SnO2 nanocomposites under natural sunlight. Biopolymer Applications Journal. 2022. Vol. 1. No. 2. P. 19—23.
Ikhlaq A., Anwar H.Z., Javed F., Gull S. Degradation of safranin by heterogeneous Fenton processes using peanut shell ash based catalyst. Water Science & Technology. 2019. Vol. 79(7). P. 1367—1375. doi.org/10.2166/wst.2019.132
Guo S., Zhang L., Chen M., Ahmad F., Fida H., Zhang H. Heterogeneous activation of peroxymonosulfate by a spinel CoAl2O4 catalyst for the degradation of organic pollutants. Catalysts. 2022. Vol. 12(8). 847. doi.org/10.3390/catal12080847
Dharini M., Jaspin S., Mahendran R. Cold plasma reactive species: Generation, properties, and interaction with food biomolecules. Food Chemistry. 2023. Vol. 405. Part A. 134746. doi.org/10.1016/j.foodchem.2022.134746
Guo S., Wang H., Yang W., Fida H., You L., Zhou K. Scalable synthesis of Ca-doped α-Fe2O3 with abundant oxygen vacancies for enhanced degradation of organic pollutants through peroxymonosulfate activation. Applied Catalysis B: Environmental. 2020. Vol. 262. 118250. doi.org/10.1016/j.apcatb.2019.118250
Xie H., Xu V. Enhanced activation of persulfate by meso-CoFe2O4/SiO2 with ultrasonic treatment for degradation of chlorpyrifos. ACS Omega. 2019. Vol. 4(17). P. 17177—17185. doi.org/10.1021/acsomega.9b01626
Guo Z., Wang X., Yang F., Liu Z. Synergistic effect of Co and Fe bimetallic oxides/hydroxides composite structure as a bifunctional electrocatalyst for enhancing overall water splitting performance. Journal of Alloys and Compounds. 2022. Vol. 895. Part 2. 162614. doi.org/10.1016/j.jallcom.2021.162614
Li J., Shi Q., Zhao R., Liu Y., Liu P., Liu L. Facile synthesis of CoMn2O4 spinel catalyst as peroxymonosulfate activator for efficient rhodamine B degradation. Materials Letters. 2023. Vol. 351. 135108. doi.org/10.1016/j.matlet.2023.135108
Liu F., Li W., Wu D., Tian T., Wu J.-F., Dong Z.-M., Zhao G.-C. New insight into the mechanism of peroxymonosulfate activation by nanoscaled lead-based spinel for organic matters degradation: A singlet oxygen-dominated oxidation process. Journal of Colloid and Interface Science. 2020. Vol. 572. P. 318—327. doi.org/10.1016/j.jcis.2020.03.116
Wang B., Li Q., Lv Y., Fu H., Liu D., Feng Y., Xie H., Qu H. Insights into the mechanism of peroxydisulfate activated by magnetic spinel CuFe2O4/SBC as a heterogeneous catalyst for bisphenol S degradation. Chemical Engineering Journal. 2021. Vol. 416. 129162. doi.org/10.1016/j.cej.2021.129162
Zheng H., Zhang Y., Lu M., Xie H., Ye J., Wang H., Yang M., Li G. Zero-valent iron-loaded Ti3C2-MXene activated by persulfate for the degradation of tetracycline hydrochloride: Efficiency and mechanism. Journal of Environmental Chemical Engineering. 2024. Vol. 12. No. 4. 113265. doi.org/10.1016/j.jece.2024.113265
Chen X., Hu C., Hong F., Fang Y., Yuan X., Tian H., Huang Y. Activation of persulfate with hydrodynamic cavitation in the removal of atrazine: Regulating the concentration of •OH and •SO4- and the degradation mechanism. Journal of Water Process Engineering. 2024. Vol. 65. 105828. doi.org/10.1016/j.jwpe.2024.105828
Sukhatskiy Y., Dmytrenko T., Shepida M., Sozanskyi M., Znak Z. Degradation of diazine dye safranin T using potassium persulfate activated by ultrasonic treatment and MnFe2O4 spinel nanoparticles. Voprosy khimii i khimicheskoi tekhnologii. 2024. No. 1(152). P. 99—108. doi.org/10.32434/0321-4095-2024-152-1-99-108
Shao Z., Xiang K., Liu S., Hong F., Gao Y., Lei E., Jia J., Huang Y. Unveiling the roles of turbulence characteristics on the degradation of methylene blue by the activation of H2O2 through vortex-based hydrodynamic cavitation under neutral condition. Journal of Environmental Chemical Engineering. 2024. Vol. 12. No. 5. 113916. doi.org/10.1016/j.jece.2024.113916
Pourzamani H., Jafari E., Rozveh M.S., Mohammadi H., Rostami M., Mengelizadeh N. Degradation of ciprofloxacin in aqueous solution by activating the peroxymonosulfate using graphene based on CoFe2O4. Desalination and Water Treatment. 2019. Vol. 167. P. 156—169. doi.org/10.5004/dwt.2019.24593
Shu Y., Zhang P., Zhong Y., Xu X., Ren G., Wang W., Xiang H., Zhang Z., Yang X., Wang X. Heterogeneous activation of persulfate by ZnCoxFe2-xO4 loaded on rice hull carbon for degrading bisphenol A. RSC Advances. 2020. Vol. 10. 44551. doi.org/10.1039/d0ra08852h
Xu J., Cheng H., Zhang H., Sun C., Tian H., Yang J., Ding Y., Lin X., Wang P., Huang C. Visible light irradiation enhanced sulfidated zero-valent iron/peroxymonosulfate process for organic pollutant degradation. Environmental Research. 2024. Vol. 257. 119292. doi.org/10.1016/j.envres.2024.119292
Hassan, A.F., Alshandoudi, L.M., Awad, A.M., Mustafa, A.A., & Esmail, G. (2023). Synthesis of nanomagnetite/copper oxide/potassium carrageenan nanocomposite for the adsorption and Photo Fenton degradation of Safranin O: kinetic and thermodynamic studies. Macromolecular Research. Vol. 31. P. 677—697. doi.org/10.1007/s13233-023-00147-4
Salem, M.A., Salem, I.A., Zaki, H.M., & El-Sawy, A.M. (2022). Elimination of Safranin-O and a binary mixture of Safranin-O and methylene blue from water by adsorption on magnetite/Ag nanocomposite. Egyptian Journal of Petroleum. Vol. 31. No. 2. P. 39—49. doi.org/10.1016/j.ejpe.2022.05.002
Bendjama, M., Hamdaoui, O., Ferkous, H., & Alghyamah, A. (2022). Degradation of safranin O in water by UV/TiO2/IO4- process: Effect of operating conditions and mineralization. Catalysts. Vol. 12(11). 1460. doi.org/10.3390/catal12111460
Jadhav, G.K.P., Malusare, O.S.A., Ahiwale, R.K.P., Patil, P., Grouli, A., Berrada, M., & Pandit, V.R.U. (2022). Safranin dye degradation by using Fe2O3-SnO2 nanocomposites under natural sunlight. Biopolymer Applications Journal. Vol. 1. No. 2. P. 19—23.
Ikhlaq, A., Anwar, H.Z., Javed, F., & Gull, S. (2019). Degradation of safranin by heterogeneous Fenton processes using peanut shell ash based catalyst. Water Science & Technology. Vol. 79(7). P. 1367—1375. doi.org/10.2166/wst.2019.132
Guo, S., Zhang, L., Chen, M., Ahmad, F., Fida, H., & Zhang H. (2022). Heterogeneous activation of peroxymonosulfate by a spinel CoAl2O4 catalyst for the degradation of organic pollutants. Catalysts. Vol. 12(8). 847. doi.org/10.3390/catal12080847
Dharini, M., Jaspin, S., & Mahendran, R. (2023). Cold plasma reactive species: Generation, properties, and interaction with food biomolecules. Food Chemistry. Vol. 405. Part A. 134746. doi.org/10.1016/j.foodchem.2022.134746
Guo, S., Wang, H., Yang, W., Fida, H., You, L., & Zhou, K. (2020). Scalable synthesis of Ca-doped α-Fe2O3 with abundant oxygen vacancies for enhanced degradation of organic pollutants through peroxymonosulfate activation. Applied Catalysis B: Environmental. Vol. 262. 118250. doi.org/10.1016/j.apcatb.2019.118250
Xie, H., & Xu, V. (2019). Enhanced activation of persulfate by meso-CoFe2O4/SiO2 with ultrasonic treatment for degradation of chlorpyrifos. ACS Omega. 2019. Vol. 4(17). P. 17177—17185. doi.org/10.1021/acsomega.9b01626
Guo, Z., Wang, X., Yang, F., & Liu, Z. (2022). Synergistic effect of Co and Fe bimetallic oxides/hydroxides composite structure as a bifunctional electrocatalyst for enhancing overall water splitting performance. Journal of Alloys and Compounds. Vol. 895. Part 2. 162614. doi.org/10.1016/j.jallcom.2021.162614
Li, J., Shi, Q., Zhao, R., Liu, Y., Liu, P., & Liu, L. (2023). Facile synthesis of CoMn2O4 spinel catalyst as peroxymonosulfate activator for efficient rhodamine B degradation. Materials Letters. Vol. 351. 135108. doi.org/10.1016/j.matlet.2023.135108
Liu, F., Li, W., Wu, D., Tian, T., Wu, J.-F., Dong, Z.-M., & Zhao, G.-C. (2020). New in-sight into the mechanism of peroxymonosulfate activation by nanoscaled lead-based spinel for organic matters degradation: A singlet oxygen-dominated oxidation process. Journal of Colloid and Interface Science. Vol. 572. P. 318—327. doi.org/10.1016/j.jcis.2020.03.116
Wang, B., Li, Q., Lv, Y., Fu, H., Liu, D., Feng, Y., Xie, H., & Qu, H. (2021). Insights into the mechanism of peroxydisulfate activated by magnetic spinel CuFe2O4/SBC as a heterogeneous catalyst for bisphenol S degradation. Chemical Engineering Journal. Vol. 416. 129162. doi.org/10.1016/j.cej.2021.129162
Zheng, H., Zhang, Y., Lu, M., Xie, H., Ye, J., Wang, H., Yang, M., & Li, G. (2024). Zero-valent iron-loaded Ti3C2-MXene activated by persulfate for the degradation of tetracycline hydrochloride: Efficiency and mechanism. Journal of Environmental Chemical Engineering. Vol. 12. No. 4. 113265. doi.org/10.1016/j.jece.2024.113265
Chen, X., Hu, C., Hong, F., Fang, Y., Yuan, X., Tian, H., & Huang, Y. (2024). Activation of persulfate with hydrodynamic cavitation in the removal of atrazine: Regulating the concentration of •OH and •SO4- and the degradation mechanism. Journal of Water Process Engineering. Vol. 65. 105828. doi.org/10.1016/j.jwpe.2024.105828
Sukhatskiy, Y., Dmytrenko, T., Shepida, M., Sozanskyi, M., & Znak, Z. (2024). Degrada-tion of diazine dye safranin T using potassium persulfate activated by ultrasonic treatment and MnFe2O4 spinel nanoparticles. Voprosy khimii i khimicheskoi tekhnologii. No. 1(152). P. 99—108. doi.org/10.32434/0321-4095-2024-152-1-99-108
Shao, Z., Xiang, K., Liu, S., Hong, F., Gao, Y., Lei, E., Jia, J., & Huang, Y. (2024). Unveiling the roles of turbulence characteristics on the degradation of methylene blue by the activation of H2O2 through vortex-based hydrodynamic cavitation under neutral condition. Journal of Environmental Chemical Engineering. Vol. 12. No. 5. 113916. doi.org/10.1016/j.jece.2024.113916
Pourzamani, H., Jafari, E., Rozveh, M.S., Mohammadi, H., Rostami, M., & Mengelizadeh, N. (2019). Degradation of ciprofloxacin in aqueous solution by activating the peroxymonosulfate using graphene based on CoFe2O4. Desalination and Water Treatment. Vol. 167. P. 156—169. doi.org/10.5004/dwt.2019.24593
Shu, Y., Zhang, P., Zhong, Y., Xu, X., Ren, G., Wang, W., Xiang, H., Zhang, Z., Yang, X., & Wang, X. (2020). Heterogeneous activation of persulfate by ZnCoxFe2-xO4 loaded on rice hull carbon for degrading bisphenol A. RSC Advances. Vol. 10. 44551. doi.org/10.1039/d0ra08852h
Xu, J., Cheng, H., Zhang, H., Sun, C., Tian, H., Yang, J., Ding, Y., Lin, X., Wang, P., & Huang, C. (2024). Visible light irradiation enhanced sulfidated zero-valent iron/peroxymonosulfate process for organic pollutant degradation. Environmental Research. Vol. 257. 119292. doi.org/10.1016/j.envres.2024.119292
